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MHT CET Chemistry Aldehydes and Ketones 2026 MHT CET 2026 (16 April Shift 2)

MHT CET Chemistry Question (2026) — Solution

Question

Acetone on heating with CrO _3 mainly forms,

Options

  1. A. Acetic acid
  2. B. Ethyl alcohol
  3. C. Toluene
  4. D. Dimethyl ether

Answer

A. Acetic acid

Step-by-step solution

Ketones are generally resistant to oxidation under normal conditions. However, on vigorous heating with strong oxidizing agents like CrO _3, they undergo cleavage of the C-C bond to form carboxylic acids with fewer carbon atoms. Acetone ( CH _3 COCH _3) undergoes oxidation to form a two-carbon carboxylic acid and a one-carbon fragment which further oxidizes to carbon dioxide and water. CH _3 COCH _3 CrO _3, CH _3 COOH + CO _2 + H _2 O The main product formed is acetic acid. Answer: Acetic acid

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