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MHT CET Chemistry Amines 2026 MHT CET 2026 (19 April Shift 1)

MHT CET Chemistry Question (2026) — Solution

Question

Which from following compounds is obtained when propionamide is treated with Br _2 and concentrated aqueous KOH solution ?

Options

  1. A. CH _3 CH _2 CH _2 COOH
  2. B. CH _3 COCH _3
  3. C. CH _3 CH _2 NH _2
  4. D. CH _3 CH _2 Br

Answer

C. CH _3 CH _2 NH _2

Step-by-step solution

Propionamide is CH _3 CH _2 CONH _2. The reaction of an amide with Br _2 and concentrated aqueous KOH is known as the Hoffmann bromamide degradation reaction. In this reaction, the amide is converted into a primary amine with one carbon atom less than the parent amide. CH _3 CH _2 CONH _2 + Br _2 + 4 KOH CH _3 CH _2 NH _2 + K _2 CO _3 + 2 KBr + 2 H _2 O The product obtained is ethylamine ( CH _3 CH _2 NH _2). Answer: CH _3 CH _2 NH _2

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