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MHT CET Chemistry Amines 2026 MHT CET 2026 (13 April Shift 1)

MHT CET Chemistry Question (2026) — Solution

Question

Which from following reagents is used to prepare alkyl isocyanides from RX?

Options

  1. A. AgCN (alco)
  2. B. NH _3 (alco)
  3. C. KNO _2
  4. D. AgNO _2

Answer

A. AgCN (alco)

Step-by-step solution

Alkyl halides react with alcoholic silver cyanide ( AgCN ) to form alkyl isocyanides as the major product. AgCN is predominantly covalent in nature, so only the nitrogen atom has a lone pair of electrons available for nucleophilic attack. This leads to the formation of an alkyl isocyanide ( RNC ). R-X + AgCN R-NC + AgX In contrast, KCN gives alkyl cyanides, KNO _2 gives alkyl nitrites, and AgNO _2 gives nitroalkanes. Answer: AgCN (alco)

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