Question
Which from following reagents is used to prepare alkyl isocyanides from RX?
Which from following reagents is used to prepare alkyl isocyanides from RX?
A. AgCN (alco)
Alkyl halides react with alcoholic silver cyanide ( AgCN ) to form alkyl isocyanides as the major product. AgCN is predominantly covalent in nature, so only the nitrogen atom has a lone pair of electrons available for nucleophilic attack. This leads to the formation of an alkyl isocyanide ( RNC ). R-X + AgCN R-NC + AgX In contrast, KCN gives alkyl cyanides, KNO _2 gives alkyl nitrites, and AgNO _2 gives nitroalkanes. Answer: AgCN (alco)
Related: Chemistry — Amines · All PYQ Banks