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MHT CET Chemistry Carboxylic Acid Derivatives 2026 MHT CET 2026 (20 April Shift 2)

MHT CET Chemistry Question (2026) — Solution

Question

Identify the reason for the highest boiling point of R-COOH as compared to alkanes, ethers, alcohols and aldehydes.

Options

  1. A. Formation of carboxylate ion
  2. B. Van der waals force of attraction
  3. C. Formation of intramolecular hydrogen bonding
  4. D. Formation of intermolecular hydrogen bonding

Answer

D. Formation of intermolecular hydrogen bonding

Step-by-step solution

Carboxylic acids have higher boiling points than alkanes, ethers, alcohols, and aldehydes of comparable molecular mass. This is due to the presence of strong intermolecular hydrogen bonding in carboxylic acids. The highly polarized O-H bond, enhanced by the electron-withdrawing carbonyl group, allows carboxylic acid molecules to form strong hydrogen bonds with each other. Because of this extensive intermolecular hydrogen bonding, they often exist as dimers even in the vapor phase or in non-polar solvents, requiring more energy to separate the molecules during boiling. Answer: Formation of intermolecular hydrogen bonding

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