Quantrex Academy · Free MHT CET PYQ solutions
MHT CET Chemistry Carboxylic Acid Derivatives 2026 MHT CET 2026 (18 April Shift 1)

MHT CET Chemistry Question (2026) — Solution

Question

Identify final products in the following sequence of reactions RCOOH + R'OH H ^+ intermediate Ni , ^ H _2 Products

Options

  1. A. R'COOH + RCH _2 OH
  2. B. RCH _2 OH + R' - OH
  3. C. R'CH _2 OH + R - OH
  4. D. R - OH + R' - OH

Answer

B. RCH _2 OH + R' - OH

Step-by-step solution

The first step is the Fischer esterification reaction between a carboxylic acid and an alcohol in the presence of an acid catalyst. The reaction produces an ester as the intermediate. RCOOH + R'OH H ^+ RCOOR' + H _2 O The intermediate formed is the ester RCOOR' . The second step involves the catalytic hydrogenation (hydrogenolysis) of the ester using hydrogen gas over a nickel catalyst at high temperature. This process cleaves the ester bond, reducing the acyl group ( RCO -) to a primary alcohol and releasing the alkoxy group (- OR' ) as another alcohol. RCOOR' + 2 H _2 Ni , RCH _2 OH + R'OH Thus, the final products are RCH _2 OH and R'OH . Answer: RCH _2 OH + R' - OH

Practice more on Quantrex App →

Related: Chemistry — Carboxylic Acid Derivatives · All PYQ Banks