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MHT CET Chemistry Carboxylic Acid Derivatives 2026 MHT CET 2026 (13 April Shift 2)

MHT CET Chemistry Question (2026) — Solution

Question

Which is a weakest acid among the following ?

Options

  1. A. ( CH _3)_2 CHCOOH
  2. B. CH _3 COOH
  3. C. ClCH _2 COOH
  4. D. Cl _3 CCOOH

Answer

A. ( CH _3)_2 CHCOOH

Step-by-step solution

Acidic strength is directly proportional to the stability of the conjugate base. Electron-withdrawing groups (-I effect) stabilize the carboxylate ion and increase acidic strength, while electron-donating groups (+I effect) destabilize the carboxylate ion and decrease acidic strength. The +I effect of the isopropyl group ( CH _3)_2 CH - is greater than that of the methyl group CH _3-. Chlorine atoms exert a -I effect, which increases acidic strength. Thus, Cl _3 CCOOH and ClCH _2 COOH are stronger acids. Since ( CH _3)_2 CH - has the maximum +I effect among the given groups, it destabilizes the conjugate base the most, making ( CH _3)_2 CHCOOH the weakest acid. Answer: ( CH _3)_2 CHCOOH

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