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MHT CET Chemistry Chemical Bonding and Molecular Structure 2026 MHT CET 2026 (19 April Shift 1)

MHT CET Chemistry Question (2026) — Solution

Question

Which among the following molecule exhibits paramagnetism?

Options

  1. A. O _2
  2. B. O _3
  3. C. N _2
  4. D. F _2

Answer

A. O _2

Step-by-step solution

According to Molecular Orbital Theory, the electronic configuration of O _2 (16 electrons) is: _ 1s ^2 ^ * _ 1s ^2 _ 2s ^2 ^ * _ 2s ^2 _ 2p_z ^2 _ 2p_x ^2 _ 2p_y ^2 ^ * _ 2p_x ^1 ^ * _ 2p_y ^1 Due to the presence of two unpaired electrons in the degenerate antibonding ^ * molecular orbitals, O _2 is paramagnetic. N _2 (14 electrons) and F _2 (18 electrons) have all their electrons paired in their molecular orbitals, making them diamagnetic. O _3 (ozone) also has all its electrons paired and is diamagnetic.

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