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MHT CET Chemistry Chemical Kinetics 2026 MHT CET 2026 (15 April Shift 1)

MHT CET Chemistry Question (2026) — Solution

Question

What is the value of the slope of a graph obtained by plotting the concentration of reactant (A)_t versus time for zero order reaction?

Options

  1. A. -k
  2. B. 1/2k
  3. C. k/2.303
  4. D. 2.303/k

Answer

A. -k

Step-by-step solution

For a zero order reaction, the rate of reaction is independent of the concentration of the reactant. The integrated rate equation for a zero order reaction is given by: [A]_t = -kt + [A]_0 where [A]_t is the concentration of the reactant at time t, [A]_0 is the initial concentration, and k is the rate constant. Comparing this equation with the equation of a straight line y = mx + c, we get: y = [A]_t x = t m = -k c = [A]_0 Thus, plotting the concentration of reactant [A]_t versus time t yields a straight line with a slope of -k. Answer: -k

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