Question
Which of the following prediction is correct when the transition metal ion is colourless?
Which of the following prediction is correct when the transition metal ion is colourless?
A. it contains 0 unpaired electrons
The colour of transition metal ions is primarily due to d-d transitions, which require the presence of partially filled d-orbitals. When the d-orbitals are completely empty (d^0 configuration, e.g., Sc^ 3+ , Ti^ 4+ ) or completely filled (d^ 10 configuration, e.g., Zn^ 2+ , Cu^+), d-d transitions are not possible. In both d^0 and d^ 10 configurations, there are no unpaired electrons. Therefore, a transition metal ion is colourless when it contains 0 unpaired electrons. Answer: it contains 0 unpaired electrons
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