Question
Which of the following cations in their oxidation states forms colored compounds ?
Which of the following cations in their oxidation states forms colored compounds ?
D. V ^ 3+
The electronic configurations of the given cations are: Sc ^ 3+ (Z=21): [ Ar ] 3d^0 Ti ^ 4+ (Z=22): [ Ar ] 3d^0 Cu ^ + (Z=29): [ Ar ] 3d^ 10 V ^ 3+ (Z=23): [ Ar ] 3d^2 Cations with d^0 or d^ 10 configurations do not have unpaired electrons for d-d transitions and are generally colorless. V ^ 3+ has two unpaired electrons in its d-orbital, which allows d-d transitions, making its compounds colored. Answer: V ^ 3+
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