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MHT CET Chemistry Electrochemistry 2026 MHT CET 2026 (18 April Shift 2)

MHT CET Chemistry Question (2026) — Solution

Question

If standard reduction potential of four electrodes A, B, C, D are +2.5\, V , +3.0\, V , -2.0\, V and -1.5\, V respectively. When is the standard emf of cell maximum?

Options

  1. A. 'A' is anode and 'B' is cathode
  2. B. 'B' is anode and 'D' is cathode
  3. C. 'C' is anode and 'B' is cathode
  4. D. 'B' is anode and 'C' is cathode

Answer

C. 'C' is anode and 'B' is cathode

Step-by-step solution

The standard emf of a cell is given by E^ _ cell = E^ _ cathode - E^ _ anode . To obtain the maximum standard emf, the cathode must have the highest standard reduction potential and the anode must have the lowest standard reduction potential. Given standard reduction potentials are: E^ _ A = +2.5 V E^ _ B = +3.0 V E^ _ C = -2.0 V E^ _ D = -1.5 V The highest reduction potential is for electrode B (+3.0 V ), so B should act as the cathode. The lowest reduction potential is for electrode C (-2.0 V ), so C should act as the anode. Maximum E^ _ cell = 3.0 - (-2.0) = 5.0 V . Thus, 'C' is the anode and 'B' is the cathode. Answer: 'C' is anode and 'B' is cathode

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