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MHT CET Chemistry Electrochemistry 2026 MHT CET 2026 (17 April Shift 1)

MHT CET Chemistry Question (2026) — Solution

Question

If the emf of cell, Cu _ (s) Cu ^ 2+ _ (1M) \| Ag ^ + _ (1M) Ag is 0.463 V at 25\ ^ C and standard potential of Cu electrode is 0.337 V. Find the standard potential of Ag electrode

Options

  1. A. 0.128\ V
  2. B. -0.128\ V
  3. C. 0.8\ V
  4. D. -0.8\ V

Answer

C. 0.8\ V

Step-by-step solution

The cell representation is Cu _ (s) Cu ^ 2+ _ (1M) \| Ag ^ + _ (1M) Ag . Since the concentrations of the ions are 1\ M , the given emf is the standard emf of the cell, E^ _ cell = 0.463\ V . The standard reduction potential of the anode (Cu) is E^ _ Cu ^ 2+ / Cu = 0.337\ V . Using the relation for standard cell potential: E^ _ cell = E^ _ cathode - E^ _ anode E^ _ cell = E^ _ Ag ^ + / Ag - E^ _ Cu ^ 2+ / Cu Substituting the given values: 0.463 = E^ _ Ag ^ + / Ag - 0.337 E^ _ Ag ^ + / Ag = 0.463 + 0.337 = 0.800\ V The standard potential of the Ag electrode is 0.8\ V . Answer: 0.8\ V

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