Question
The standard potential of Cu ^ +2 / Cu is 0.34 V at 298 K. Calculate its potential at the same temperature when the Cu ^ +2 ion concentration is 0.1 M.
The standard potential of Cu ^ +2 / Cu is 0.34 V at 298 K. Calculate its potential at the same temperature when the Cu ^ +2 ion concentration is 0.1 M.
C. 0.31 V
The reduction half-reaction is Cu ^ +2 + 2e^ - Cu . Using the Nernst equation for the electrode potential: E = E^ - 0.0591 n 1 [ Cu ^ +2 ] Given E^ = 0.34 V, n = 2, and [ Cu ^ +2 ] = 0.1 M. E = 0.34 - 0.0591 2 1 0.1 E = 0.34 - 0.0295 10 E = 0.34 - 0.0295 1 E = 0.3105 V 0.31 V. Answer: 0.31 V
Related: Chemistry — Electrochemistry · All PYQ Banks