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MHT CET Chemistry General Organic Chemistry 2026 MHT CET 2026 (20 April Shift 2)

MHT CET Chemistry Question (2026) — Solution

Question

Which one of the following series contains only electrophiles?

Options

  1. A. R-OH , Cl ^+, NH _3
  2. B. H _2 O , R _2 N ^-, H _3 O ^+
  3. C. BF _3, SO _3, NO ^+
  4. D. AlCl _3, R-NH _2, PCl _3

Answer

C. BF _3, SO _3, NO ^+

Step-by-step solution

Electrophiles are electron-deficient species that can accept an electron pair. They are either positively charged or neutral molecules with an incomplete octet or highly polar bonds. In the first series, R-OH and NH _3 have lone pairs on oxygen and nitrogen respectively, making them nucleophiles. In the second series, H _2 O and R _2 N ^- have lone pairs and a negative charge respectively, making them nucleophiles. In the third series, BF _3 is an electron-deficient Lewis acid with an incomplete octet. SO _3 has a highly electron-deficient sulfur atom due to three electronegative oxygen atoms. NO ^+ is a positively charged ion. All three are electrophiles. In the fourth series, R-NH _2 has a lone pair on nitrogen, making it a nucleophile. Answer: BF _3, SO _3, NO ^+

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