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MHT CET Chemistry General Organic Chemistry 2026 MHT CET 2026 (13 April Shift 1)

MHT CET Chemistry Question (2026) — Solution

Question

The cyclic -molecular orbital formed by overlap of p-orbitals must contain,

Options

  1. A. (4n + 2) p electrons.
  2. B. (2n + 2) p electrons.
  3. C. (4n - 2) p electrons.
  4. D. (2n - 2) p electrons.

Answer

A. (4n + 2) p electrons.

Step-by-step solution

According to H 00fcckel's rule, a cyclic, planar, and completely conjugated system is highly stable and aromatic if it contains (4n + 2) -electrons, where n is an integer (0, 1, 2, ). These -electrons reside in the cyclic -molecular orbital formed by the continuous lateral overlap of unhybridized p-orbitals of the atoms in the ring. Thus, the cyclic -molecular orbital must contain (4n + 2) p electrons for the system to exhibit aromatic stability.

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