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MHT CET Chemistry General Organic Chemistry 2026 MHT CET 2026 (13 April Shift 1)

MHT CET Chemistry Question (2026) — Solution

Question

Identify the false statement regarding chirality from the following.

Options

  1. A. SN^1 reaction yields 1:1 mixture of both enantiomers
  2. B. A recemic mixture shows zero dipole rotation
  3. C. Enantiomers are superimposable mirror images of each other
  4. D. The product obtained by SN^2 reaction of haloalkane having chirality at the reactive site shows inversion of configuration

Answer

C. Enantiomers are superimposable mirror images of each other

Step-by-step solution

Enantiomers are defined as stereoisomers that are non-superimposable mirror images of each other. Therefore, the statement that enantiomers are superimposable mirror images is false. In an S_N1 reaction, the formation of a planar carbocation intermediate allows the nucleophile to attack from either face with equal probability, generally yielding a 1:1 mixture of enantiomers (a racemic mixture). A racemic mixture contains equal amounts of dextrorotatory and levorotatory enantiomers, resulting in zero net optical rotation. In an S_N2 reaction at a chiral center, the nucleophile attacks from the side opposite to the leaving group, leading to a complete inversion of configuration. Answer: Enantiomers are superimposable mirror images of each other

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