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MHT CET Chemistry Haloalkanes and Haloarenes 2026 MHT CET 2026 (20 April Shift 2)

MHT CET Chemistry Question (2026) — Solution

Question

In Finkelstein reaction, which one of the following reagents is used?

Options

  1. A. HI in dry acetone
  2. B. NaI in dry acetone
  3. C. NaOI in dry acetone
  4. D. NaI in dry ether

Answer

B. NaI in dry acetone

Step-by-step solution

The Finkelstein reaction is a halogen exchange reaction used for the synthesis of alkyl iodides from alkyl chlorides or alkyl bromides. The reaction involves treating an alkyl chloride or bromide with sodium iodide (NaI) in dry acetone. R-X + NaI dry acetone R-I + NaX where X = Cl, Br. Sodium iodide is soluble in dry acetone, whereas sodium chloride and sodium bromide are insoluble and precipitate out. This precipitation drives the forward reaction according to Le Chatelier's principle. Answer: NaI in dry acetone

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