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MHT CET Chemistry Haloalkanes and Haloarenes 2026 MHT CET 2026 (20 April Shift 2)

MHT CET Chemistry Question (2026) — Solution

Question

What is the major product formed when 2-bromopentane reacts with alcoholic KOH?

Options

  1. A. Pent-1-ene
  2. B. Pent-2-ene
  3. C. Pentane
  4. D. Pentan-2-ol

Answer

B. Pent-2-ene

Step-by-step solution

Reaction of 2-bromopentane with alcoholic KOH undergoes dehydrohalogenation (E2 elimination). CH_3-CH(Br)-CH_2-CH_2-CH_3 alc. KOH, CH_3-CH=CH-CH_2-CH_3 + CH_2=CH-CH_2-CH_2-CH_3 According to Zaitsev's rule, the more substituted alkene is formed as the major product. Pent-2-ene is a disubstituted alkene, whereas pent-1-ene is a monosubstituted alkene. Thus, pent-2-ene is the major product. Answer: Pent-2-ene

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