Question
Which from the following compounds is not obtained when methyl bromide is treated with ethyl bromide in presence of sodium metal in dry ether?
Which from the following compounds is not obtained when methyl bromide is treated with ethyl bromide in presence of sodium metal in dry ether?
D. 2-methyl propane
The reaction of methyl bromide and ethyl bromide with sodium metal in dry ether is an example of the Wurtz reaction. The alkyl free radicals formed during the reaction are methyl radical (CH_3^ ) and ethyl radical (C_2H_5^ ). These radicals can undergo self-coupling as well as cross-coupling to give a mixture of alkanes: CH_3^ + CH_3^ CH_3-CH_3 (Ethane) C_2H_5^ + C_2H_5^ CH_3-CH_2-CH_2-CH_3 (n-Butane) CH_3^ + C_2H_5^ CH_3-CH_2-CH_3 (Propane) 2-methyl propane cannot be formed by the coupling of methyl and ethyl radicals. Therefore, 2-methyl propane is not obtained in this reaction. Answer: 2-methyl propane
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