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MHT CET Chemistry Haloalkanes and Haloarenes 2026 MHT CET 2026 (16 April Shift 2)

MHT CET Chemistry Question (2026) — Solution

Question

Identify the reagent used for replacement of - N _2^+ Cl ^- from benzene diazonium chloride by iodine.

Options

  1. A. HI
  2. B. KOI
  3. C. KI
  4. D. PI _3

Answer

C. KI

Step-by-step solution

Benzene diazonium chloride reacts with aqueous potassium iodide (KI) upon warming to form iodobenzene. The reaction is given by: C _6 H _5 N _2^+ Cl ^- + KI C _6 H _5 I + N _2 + KCl Therefore, the reagent used for the replacement of the diazonium group by iodine is KI. Answer: KI

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