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MHT CET Chemistry Haloalkanes and Haloarenes 2026 MHT CET 2026 (13 April Shift 2)

MHT CET Chemistry Question (2026) — Solution

Question

What is the importance of Sandmeyer's reaction?

Options

  1. A. To obtain R-I from R-Cl
  2. B. To obtain Ar-X by replacing diazo group of AR-N _2^+ -X ^- using CuCl / HCl
  3. C. To obtain R-F from R-Cl using AgF
  4. D. To obtain R-CH _2 -R from R-CO-R using Zn-Hg / HCl

Answer

B. To obtain Ar-X by replacing diazo group of AR-N _2^+ -X ^- using CuCl / HCl

Step-by-step solution

Sandmeyer's reaction is a chemical reaction used to synthesize aryl halides from aryl diazonium salts. It involves the replacement of the diazonium group (- N _2^+) in Ar-N _2^+ X ^- by a halogen atom (such as Cl or Br) or a cyanide group using copper(I) salts like CuCl / HCl , CuBr / HBr , or CuCN / KCN . The reaction to obtain R-I from R-Cl is known as the Finkelstein reaction. The reaction to obtain R-F from R-Cl using AgF is known as the Swarts reaction. The reaction to obtain R-CH _2 -R from R-CO-R using Zn-Hg / HCl is known as the Clemmensen reduction. Therefore, Sandmeyer's reaction is used to obtain Ar-X by replacing the diazo group of Ar-N _2^+ X ^- using CuCl / HCl . Answer: To obtain Ar-X by replacing diazo group of AR-N _2^+ -X ^- using CuCl / HCl

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