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MHT CET Chemistry Haloalkanes and Haloarenes 2026 MHT CET 2026 (11 April Shift 2)

MHT CET Chemistry Question (2026) — Solution

Question

Identify the major product of dehydrohalogenation of CH _3 -CH _2 -CH(Br)-CH _3.

Options

  1. A. CH _3 -CH _2 -CH=CH _2
  2. B. H _3 C-CH=CH-CH _3
  3. C. CH _3 -(CH _2)_2 CH _3
  4. D. CH _3 -(CH _2)_2 CHO

Answer

B. H _3 C-CH=CH-CH _3

Step-by-step solution

Dehydrohalogenation of 2-bromobutane ( CH _3 -CH _2 -CH(Br)-CH _3) involves the removal of a hydrogen atom from a -carbon and the bromine atom from the -carbon. There are two -carbons in 2-bromobutane, leading to two possible alkene products: 1. Removal of hydrogen from C1 yields 1-butene ( CH _3 -CH _2 -CH=CH _2). 2. Removal of hydrogen from C3 yields 2-butene ( CH _3 -CH=CH-CH _3). According to Zaitsev's rule, the major product in a dehydrohalogenation reaction is the more substituted alkene, as it is thermodynamically more stable. 2-butene is a disubstituted alkene, whereas 1-butene is a monosubstituted alkene. Thus, 2-butene ( H _3 C-CH=CH-CH _3) is the major product. Answer: H _3 C-CH=CH-CH _3

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