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MHT CET Chemistry Hydrocarbons 2026 MHT CET 2026 (18 April Shift 1)

MHT CET Chemistry Question (2026) — Solution

Question

Which of the following alkyl chlorides on Wurtz reaction gives 2, 2, 5, 5- tetramethylhexane ?

Options

  1. A. ( CH _3)_2 CH - CH _2- Cl
  2. B. ( CH _3)_3 C - CH _2- Cl
  3. C. ( CH _3)_2 CH - CH _3 | CH - Cl
  4. D. CH _3- CH _2- Cl | CH - CH _3

Answer

B. ( CH _3)_3 C - CH _2- Cl

Step-by-step solution

Wurtz reaction involves the coupling of two alkyl halide molecules in the presence of sodium and dry ether to form a symmetrical alkane. 2 R-Cl + 2 Na dry ether R-R + 2 NaCl The given product is 2,2,5,5-tetramethylhexane. Its structure is ( CH _3)_3 C - CH _2- CH _2- C ( CH _3)_3. Cleaving the molecule symmetrically at the central C - C bond gives two identical alkyl groups, which are neopentyl groups, ( CH _3)_3 C - CH _2-. Therefore, the required alkyl chloride is neopentyl chloride, ( CH _3)_3 C - CH _2- Cl . Answer: ( CH _3)_3 C - CH _2- Cl

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