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MHT CET Chemistry Solid State 2026 MHT CET 2026 (19 April Shift 2)

MHT CET Chemistry Question (2026) — Solution

Question

Calculate the total volume of simple cubic unit cell in cm ^3 if void volume is 2.0 10^ -23 \, cm ^3

Options

  1. A. 4.2 10^ -23
  2. B. 3.8 10^ -23
  3. C. 3.4 10^ -23
  4. D. 4.6 10^ -23

Answer

A. 4.2 10^ -23

Step-by-step solution

For a simple cubic unit cell, the relation between edge length a and radius of the atom r is a = 2r. The packing fraction is given by Volume of atoms Total volume = 4 3 r^3 a^3 = 4 3 r^3 8r^3 = 6 0.524. The fraction of void volume in the unit cell is 1 - 0.524 = 0.476. Given the void volume is 2.0 10^ -23 \, cm ^3. Total volume of the unit cell V = Void volume Fraction of void volume = 2.0 10^ -23 0.476 . V 4.2 10^ -23 \, cm ^3. Answer: 4.2 10^ -23

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