Question
Calculate the van't Hoff factor of a centimolar solution of potassium ferrocyanide if it is 60\% dissociated at 300 K.
Calculate the van't Hoff factor of a centimolar solution of potassium ferrocyanide if it is 60\% dissociated at 300 K.
A. 3.4
The chemical formula of potassium ferrocyanide is K_4[Fe(CN)_6]. The dissociation reaction is: K_4[Fe(CN)_6] 4K^+ + [Fe(CN)_6]^ 4- The number of ions produced per formula unit, n = 5. The degree of dissociation, = 60\% = 0.60. The van't Hoff factor i is given by: i = 1 + (n - 1) Substituting the values: i = 1 + (5 - 1) 0.60 i = 1 + 4 0.60 i = 1 + 2.4 = 3.4 Answer: 3.4
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