Question
Identify the reactions which give aniline as the major product. Choose the correct answer from the options given below.
Identify the reactions which give aniline as the major product. Choose the correct answer from the options given below.
C. B and D only
Let us analyze each reaction to determine the major product: Reaction A: Benzonitrile (C_6H_5CN) is reduced by LiAlH_4, a strong reducing agent, to form benzylamine. C_6H_5CN LiAlH_4 C_6H_5CH_2NH_2 Reaction B: Benzamide (C_6H_5CONH_2) undergoes Hoffmann bromamide degradation in the presence of KOH and Br_2 to form aniline. C_6H_5CONH_2 KOH, Br_2 C_6H_5NH_2 Reaction C: Nitrobenzene (C_6H_5NO_2) is not reduced to aniline by NaBH_4. NaBH_4 is a mild reducing agent and generally does not reduce the -NO_2 group. Reaction D: Acetanilide (C_6H_5NHCOCH_3) undergoes acid-catalyzed hydrolysis upon heating to yield aniline and acetic acid. C_6H_5NHCOCH_3 HCl, H_2O, C_6H_5NH_2 + CH_3COOH Thus, reactions B and D give aniline as the major product. Answer: B and D only
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