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NEET Chemistry Amines 2026 NEET 2026 (Cancelled)

NEET Chemistry Question (2026) — Solution

Question

The major product Z formed in the following sequence of reactions is : C _2 H _6 [ UV light ] Cl _2 X NH _3 Y [( monochlorinated product )] (i) NaNO _2/ HCl \ \ (ii) H _2 O Z

Options

  1. A. C _2 H _5 NO _2
  2. B. C _2 H _5-N=N- OH
  3. C. C _2 H _5 OH
  4. D. C _2 H _5 NH _2

Answer

C. C _2 H _5 OH

Step-by-step solution

Ethane undergoes free radical halogenation with chlorine in the presence of UV light to form ethyl chloride (X). C _2 H _6 + Cl _2 UV light C _2 H _5 Cl \ (X) Ethyl chloride reacts with ammonia via nucleophilic substitution to form ethylamine (Y). C _2 H _5 Cl + NH _3 C _2 H _5 NH _2 \ (Y) Ethylamine, being a primary aliphatic amine, reacts with nitrous acid ( NaNO _2 + HCl ) to form an unstable aliphatic diazonium salt, which decomposes to yield a carbocation. The carbocation reacts with water to form ethanol (Z). C _2 H _5 NH _2 NaNO _2/ HCl [ C _2 H _5 N _2^ + Cl ^ - ] H _2 O C _2 H _5 OH \ (Z) + N _2 + HCl Thus, the major product Z is C _2 H _5 OH . Answer: C _2 H _5 OH

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