Quantrex Academy · Free NEET PYQ solutions
NEET Chemistry Chemical Bonding and Molecular Structure 2026 NEET 2026 (Cancelled)

NEET Chemistry Question (2026) — Solution

Question

Identify the correct statement about ClF _3 from the following options :

Options

  1. A. It has T-shaped geometry with two lone pairs on Cl atom.
  2. B. It has T-shaped geometry with three lone pairs on Cl atom.
  3. C. It has a trigonal pyramidal geometry with two lone pairs on Cl atom.
  4. D. It has a planar trigonal geometry with two lone pairs on Cl atom.

Answer

A. It has T-shaped geometry with two lone pairs on Cl atom.

Step-by-step solution

The central atom in ClF _3 is Chlorine (Cl). Number of valence electrons of Cl = 7. Number of monovalent atoms (F) attached = 3. Steric number = 1 2 (7 + 3) = 5. The hybridization of the central atom is sp^3d. Number of bond pairs = 3. Number of lone pairs = 5 - 3 = 2. The electron geometry is trigonal bipyramidal. According to VSEPR theory, to minimize repulsion, the two lone pairs occupy the equatorial positions. This results in a T-shaped molecular geometry. Therefore, ClF _3 has a T-shaped geometry with two lone pairs on the Cl atom. Answer: It has T-shaped geometry with two lone pairs on Cl atom.

Practice more on Quantrex App →

Related: Chemistry — Chemical Bonding and Molecular Structure · All PYQ Banks