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NEET Chemistry Coordination Compounds 2026 NEET 2026 (Re-NEET)

NEET Chemistry Question (2026) — Solution

Question

The formula of tetraammineaquachloridocobalt(III) chloride is

Options

  1. A. [ Co(NH _3)_4( H _2 O ) Cl ] Cl _2
  2. B. [ Co(NH _3)_4 Cl _2] H _2 O
  3. C. [ Co(NH _3)_4] Cl _3 H _2 O
  4. D. [ Co(NH _3)_4( H _2 O ) Cl ] Cl

Answer

A. [ Co(NH _3)_4( H _2 O ) Cl ] Cl _2

Step-by-step solution

The complex name is tetraammineaquachloridocobalt(III) chloride. The central metal ion is cobalt(III), which means Co is in the +3 oxidation state. The ligands inside the coordination sphere are four ammine ( NH _3) molecules which are neutral, one aqua ( H _2 O ) molecule which is neutral, and one chlorido ( Cl ^-) ion which has a -1 charge. The coordination sphere is [ Co ( NH _3)_4( H _2 O ) Cl ]. The charge on the complex ion is calculated as +3 + 4(0) + 0 + (-1) = +2. To balance the +2 charge of the complex ion, two chloride ( Cl ^-) counter ions are required outside the coordination sphere. Thus, the formula of the complex is [ Co ( NH _3)_4( H _2 O ) Cl ] Cl _2. Answer: [ Co(NH _3)_4( H _2 O ) Cl ] Cl _2

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