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NEET Chemistry Haloalkanes and Haloarenes 2024 NEET 2024 (Re-NEET)

NEET Chemistry Question (2024) — Solution

Question

The following reaction method is not suitable for the preparation of the corresponding haloarene products, due to high reactivity of halogen, when X is :

Options

  1. A. F
  2. B. I
  3. C. Cl
  4. D. Br

Answer

A. F

Step-by-step solution

- Aryl chlorides and bromides can easily be prepared by electrophilic substitution of arenes (toluene) with Cl _2 and Br _2 respectively in the presence of Lewis acid catalyst ( Fe in dark). - Reaction with I _2 is reversible and requires the presence of oxidising agent. - Corresponding fluoroarene is not prepared by this method due to high reactivity of fluorine. Hence, ' X ' is F.

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