(A)
100 gCaCO3 decomposition ⟶CaO+22.4 LCO2∵100 gCaCO3 on decomposition gives =22.4 LCO2=10022.4×10LCO2=2.24 LCO2\therefore 10 \mathrm{~g} \mathrm{CaCO}_3
ondecompositionwillgive=10022.4×10LCO2=2.24LCO2(B)Na2CO3⟶ Excess HCl2NaCl+H2O+CO2106 g22.4 L106 gNa2CO3 gives =22.4 LCO21.06 gNa2CO3 will give =10622.4×1.06 LCO2=0.224 LCO2$\begin{aligned}
& =\frac{22.4 \times 1.06}{106} \mathrm{LCO}_2 \\
& =0.224 \mathrm{~L} \mathrm{CO}_2
\end{aligned}(C)12 \mathrm{~g}
carbononcombustiongives=22.4 \mathrm{~L} \mathrm{CO}_22.4 \mathrm{~g}
carbononcombustionwillgive=1222.4×2.4LCO2=2×2.24LCO2=4.48LCO2(D)56 \mathrm{~g}
carbonmonoxideoncombustiongives=2 \times 22.4 \mathrm{~L} \mathrm{CO}_20.56 \mathrm{~g}
carbonmonoxideoncombustionwillgive=562×22.4×0.56LCO2=0.448LCO2$
Hence, A-(iv), B-(i), C-(ii), D-(iii)