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NEETChemistryStructure of Atom

Match List I with List II regarding the radial probability distribution curves ( 4 r^2 ^2 vs r ). List I (Orbital) List II (Number of maxima/peaks) (A) 2p (I) 1 (B) 3s (II) 2 (C) 4d (III) 3 (D) 4s (IV) 4 Choose the correct answer from the options given below:

Options

  1. A(A)-(I), (B)-(II), (C)-(III), (D)-(IV)
  2. B(A)-(I), (B)-(III), (C)-(II), (D)-(IV)
  3. C(A)-(II), (B)-(I), (C)-(IV), (D)-(III)
  4. D(A)-(I), (B)-(III), (C)-(IV), (D)-(II)

Correct answer

B. (A)-(I), (B)-(III), (C)-(II), (D)-(IV)

Step-by-step solution

The number of maxima (peaks) in the radial probability distribution curve ( 4 r^2 ^2 versus r ) for an orbital is equal to the number of radial nodes plus one. Number of peaks = (n - l - 1) + 1 = n - l . Calculating the number of peaks for each given orbital: (A) 2p : n = 2 , l = 1 . Number of peaks = 2 - 1 = 1 . Matches with (I). (B) 3s : n = 3 , l = 0 . Number of peaks = 3 - 0 = 3 . Matches with (III). (C) 4d : n = 4 , l = 2 . Number of peaks = 4 - 2 = 2 . Matches with (II). (D) 4s : n = 4 , l = 0 . Number of pea

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