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NEET2018ChemistryRedox ReactionsActual

When CH ₃ COOCH ₃+ HCl is titrated with NaOH then at neutral point the colour of phenolphthalein becomes colourless from pink due to

Options

  1. Aformation of CH ₃ OH
  2. Bformation of CH ₃ COOH which acts as a weak acid
  3. Cphenolphthalein vaporizes
  4. Dpresence of HCl .

Correct answer

B. formation of CH ₃ COOH which acts as a weak acid

Step-by-step solution

NaOH solution is taken in a conical flask with phenolphthalein indicator (pink colour) and CH ₃ COOCH ₃+ HCl solution is added from burette slowly. First, HCl left after hydrolysis of ester (being a strong acid) gets consumed then CH ₃ COOH being a weak acid will bring the titration to the neutralisation point. aligned & CH ₃ COOCH ₃ H ₂ O H ⁺ CH ₃ COOH + CH ₃ OH & HCl + NaOH NaCl + H ₂ O & CH ₃ COOH + NaOH CH ₃ COONa aligned

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