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- s Block Elements
NEET · Chemistry · s Block Elements
Why is lithium carbonate (Li 2 CO 3 ) less stable to heat compared...
Why is lithium carbonate (Li2CO3) less stable to heat compared to other alkali metal carbonates?
Options
- ALithium carbonate is inherently less stable due to its composition.
- BLithium carbonate is more stable to heat than other alkali metal carbonates.
- CLithium carbonate decomposes into Li2O and CO2 when heated due to its small size polarizing CO32- ions.
- DLithium carbonate does not undergo any thermal decomposition.
Correct answer
C. Lithium carbonate decomposes into Li2O and CO2 when heated due to its small size polarizing CO32- ions.
Step-by-step solution
Lithium carbonate (Li2CO3) is less stable to heat because lithium ions, being very small in size, polarize the carbonate ion (CO32-), leading to the formation of more stable lithium oxide (Li2O) and carbon dioxide (CO2) when heated.