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NEET2003Chemistrys Block ElementsActual

On dissolving moderate amount of sodium metal in liquid NH ₃ at low temperature, which one of the following does not occur?

Options

  1. ABlue coloured solution is obtained.
  2. BNa ⁺ ions are formed in the solution.
  3. CLiquid NH ₃ becomes good conductor of electricity.
  4. DLiquid ammonia remains diamagnetic.

Correct answer

D. Liquid ammonia remains diamagnetic.

Step-by-step solution

The alkali metals dissolve in liquid ammonia without evolution of hydrogen. The colour of the dilute solution is blue and are paramagnetic in nature. M M⁺ (in liquid ammonia) +e⁻ (ammoniated) M+(x+y) NH ₃ [M ( NH ₃ )_x ]⁺+e⁻ ( NH ₃ )_y solvated electron

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