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NEETChemistryChemical Kinetics

The kinetic study of a reaction like v A P at 300 K provides the following curve, where concentration is taken in mol dm ⁻³ and time in min. Identify the correct order (n) and rate constant (k)

Options

  1. An=0, k=4.0 mol dm ⁻³ min ⁻¹
  2. Bn=1 / 2, k=2.0 mol ^ 1 / 2 dm ^ -3 / 2 min ⁻¹
  3. Cn=1, k=80 min ⁻¹
  4. Dn=2, k=16.0 dm ³ mol ⁻¹ min ⁻¹

Correct answer

D. n=2, k=16.0 dm ³ mol ⁻¹ min ⁻¹

Step-by-step solution

From the given graph Slope = ( rate )^ 1 / 2 [A] =4 rate (r)=k[A]^ n Where, k= rate constant [A]= concentration at time t (in min). n= order. According to the graph (n=2) k= rate [A]^ n =[4]²=16 Hence, n=2 and k=16.0 dm ³ mol ⁻¹ ⁻¹ and option (d) is the correct answer.

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