NEETChemistryChemical Kinetics
For a zero order reaction, the rate constant is 1.5 10⁻³ mol L ⁻¹ s ⁻¹ . If the half-life of the reaction is 100 s , what is the initial concentration of the reactant?
Options
- A0.15 M
- B0.075 M
- C1.5 10⁻⁵ M
- D0.30 M
Correct answer
D. 0.30 M
Step-by-step solution
For a zero order reaction, the half-life is given by: t_ 1/2 = [A]₀ 2k Rearranging for initial concentration [A]₀ : [A]₀ = 2 k t_ 1/2 Substituting the given values: [A]₀ = 2 (1.5 10⁻³ mol L ⁻¹ s ⁻¹) 100 s [A]₀ = 3.0 10⁻³ 100 = 0.30 M Answer: 0.30 M