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NEETChemistryChemical Kinetics

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): For a zero-order reaction, the unit of the rate constant is identical to the unit of the rate of reaction. Reason (R): For a zero-order reaction, the rate of reaction is directly proportional to the concentration of the reactants. In the light of the above statements, choose the most appropriate an

Options

  1. ABoth Assertion (A) and Reason (R) are correct and Reason (R) is the correct explanation of Assertion (A).
  2. BBoth Assertion (A) and Reason (R) are correct but Reason (R) is not the correct explanation of Assertion (A).
  3. CAssertion (A) is correct but Reason (R) is not correct.
  4. DAssertion (A) is not correct but Reason (R) is correct.

Correct answer

C. Assertion (A) is correct but Reason (R) is not correct.

Step-by-step solution

Assertion (A) is correct: The unit of the rate of reaction is always mol L ⁻¹ s ⁻¹ . For a zero-order reaction, the rate equation is Rate = k[ Reactant ]^0 = k . Since the concentration term becomes 1 , the unit of the rate constant k is exactly the same as the unit of the rate of reaction, which is mol L ⁻¹ s ⁻¹ . Reason (R) is not correct: By definition, a zero-order reaction is one wherein the rate of the reaction is independent of the concentration of the reactants. It is not directly proportional to the concen

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