NEETChemistryChemical Kinetics
Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): For a zero-order reaction, the unit of the rate constant is identical to the unit of the rate of reaction. Reason (R): For a zero-order reaction, the rate of reaction is directly proportional to the concentration of the reactants. In the light of the above statements, choose the most appropriate an
Options
- ABoth Assertion (A) and Reason (R) are correct and Reason (R) is the correct explanation of Assertion (A).
- BBoth Assertion (A) and Reason (R) are correct but Reason (R) is not the correct explanation of Assertion (A).
- CAssertion (A) is correct but Reason (R) is not correct.
- DAssertion (A) is not correct but Reason (R) is correct.
Correct answer
C. Assertion (A) is correct but Reason (R) is not correct.
Step-by-step solution
Assertion (A) is correct: The unit of the rate of reaction is always mol L ⁻¹ s ⁻¹ . For a zero-order reaction, the rate equation is Rate = k[ Reactant ]^0 = k . Since the concentration term becomes 1 , the unit of the rate constant k is exactly the same as the unit of the rate of reaction, which is mol L ⁻¹ s ⁻¹ . Reason (R) is not correct: By definition, a zero-order reaction is one wherein the rate of the reaction is independent of the concentration of the reactants. It is not directly proportional to the concen