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NEET2007ChemistryChemical KineticsActual

Assertion : The kinetics of the reaction (m A+n B+p C m^ X+n^ Y+p^ Z ) obeys the rate expression as - ( d x d t =k[A]^m[B]^n ) Reason : The rate of reaction does not depend upon the concentration of (C ).

Options

  1. AIf both assertion and reason are true and reason is the correct explanation of assertion.
  2. BIf both assertion and reason are true but reason is not the correct explanation of assertion.
  3. CIf assertion is true but reason is false.
  4. DIf both assertion and reason are false.

Correct answer

A. If both assertion and reason are true and reason is the correct explanation of assertion.

Step-by-step solution

Rate expression ( d x d t =k[A]^m[B]^n ) shows that the total order of reactions is (m+n+0=m+n ) as the rate of reaction is independent of concentration of (C ), i.e, the order with respect to (C ) is zero. This is the reason that (C ) does not figure in the rate expression.

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