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NEETChemistryd and f Block Elements

For the first-row transition metals, the E ⊖ values are: E ⊖ V Cr Mn Fe Co Ni Cu (M 2+ /M) –1.18 –0.91 –1.18 –0.44 –0.28 –0.25 +0.34 Which of the following options explain the irregularity in the above values?

Options

  1. AThe number of valence electrons increases uniformly across the series.
  2. BAll transition metals have the same effective nuclear charge.
  3. Ccan be explained by the irregular variation of ionization enthalpies and also the sublimation enthalpies which
  4. DThe ionization energy decreases uniformly from V to Cu.

Correct answer

C. can be explained by the irregular variation of ionization enthalpies and also the sublimation enthalpies which

Step-by-step solution

Correct Option is : (C) can be explained by the irregular variation of ionization enthalpies and also the sublimation enthalpies which are relatively much less for manganese and vanadium.

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