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NEETChemistryd and f Block Elements

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): Terbium (IV) acts as an oxidant in aqueous solution. Reason (R): The +4 oxidation state of Terbium is favoured by its noble gas core electronic configuration. In the light of the above statements, choose the most appropriate answer from the options given below:

Options

  1. ABoth Assertion and Reason are correct and Reason is the correct explanation for Assertion.
  2. BBoth Assertion and Reason are correct but Reason is not the correct explanation for Assertion.
  3. CAssertion is correct but Reason is incorrect.
  4. DAssertion is incorrect but Reason is correct.

Correct answer

C. Assertion is correct but Reason is incorrect.

Step-by-step solution

Assertion (A) is correct: Terbium (Tb) can show a +4 oxidation state, but the most stable oxidation state for all lanthanoids is +3 . Thus, Tb⁴⁺ readily accepts an electron to become Tb³⁺ , acting as a strong oxidant in aqueous solutions. Reason (R) is incorrect: The atomic number of Terbium is 65 . The electronic configuration of Tb is [Xe] 4f⁹ 6s² . In the +4 oxidation state, the configuration of Tb⁴⁺ is [Xe] 4f⁷ . This represents a stable half-filled f -subshell, not a noble gas core configuration (which would b

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