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NEET2017Chemistryd and f Block ElementsActual

When I ⁻ is oxidised by MnO ₄⁻ in alkaline medium, I ⁻ converts into

Options

  1. AIO ₃⁻
  2. BI₂
  3. CIO ₄⁻
  4. DI0⁻

Correct answer

A. IO ₃⁻

Step-by-step solution

When I ⁻ is oxidised by MnO ₄⁻ in alkaline medium, I ⁻ converts into IO ₃⁻ . The reaction occurs as follows. gathered 2 KMnO ₄+2 KOH K ₂ MnO ₄+ H ₂ O +[ O ] [2] K ₂ MnO ₄+2 H ₂ O 2 MnO ₂+4 KOH +2[ O ] 2 KMO ₄+ H ₂ O Alkaline 2 MnO ₂+2 KOH +3[O] gathered KI +3[ O ] KIO ₃ i.e. IO ₃⁻ -ion

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