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Starch gives a characteristic blue colour when treated with iodine solution. Which of the following structural features of starch is responsible for this phenomenon?

Options

  1. AIt is a heteropolymer composed of multiple types of monosaccharides.
  2. BIt forms covalent bonds with iodine molecules upon reaction.
  3. CIt forms helical secondary structures that can hold iodine molecules.
  4. DIt consists of highly branched chains without any secondary structure.

Correct answer

C. It forms helical secondary structures that can hold iodine molecules.

Step-by-step solution

According to NCERT, starch forms helical secondary structures. These helices act as a trap, holding the iodine ( I₂ ) molecules inside the helical portion, which results in the characteristic blue colour. Starch does not form covalent bonds with iodine, nor is it a heteropolymer (it is a homopolymer of glucose). While amylopectin in starch is branched, it is the presence of helical secondary structures that allows it to hold iodine. Answer: It forms helical secondary structures that can hold iodine molecules.

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