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BITSAT2020ChemistryAlcohols Phenols and EthersActual

On reaction with sodium, 1 mol of a compound X gives 1 ~mol of H ₂ . Which one of the following compounds might be X ?

Options

  1. ACH ₃ CH ₂ CH = CH ₂
  2. BCH ₃ COOCH ₂ CH ₃
  3. CCH ₃ CH ₂ CH ₂ OH
  4. DCH ₂( OH ) CH ₂ CH ₂ CH ₂ OH

Correct answer

D. CH ₂( OH ) CH ₂ CH ₂ CH ₂ OH

Step-by-step solution

Since 1 mole of compound Xreacts with Na to evolve 1 mole of H ₂ gas, therefore the compound should have 2 active hydrogen atoms per mole which is possible only in option d . array l CH ₂ OHCH ₂ CH ₂ CH ₂ OH +2 Na NaOCH ₂ CH ₂ CH ₂ CH ₂ ONa +2 H array

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