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BITSAT 2018
Exam
BITSAT
Year
2018
Subject
Chemistry
Chapter
Aldehydes and Ketones

BITSAT 2018 · Chemistry · Aldehydes and Ketones

An unsaturated hydrocarbon ' X ' gives white precipitate with...

An unsaturated hydrocarbon ′X′' X 'gives white precipitate with Tollen's reagent. If XX is gaseous in nature, the molecular formula of XX is

Options

  1. AC3H6{C}_{3}{H}_{6}
  2. BC2H4{C}_{2}{H}_{4}
  3. CC2H2{C}_{2}{H}_{2}
  4. DC4H8{C}_{4}{H}_{8}

Correct answer

C. C2H2{C}_{2}{H}_{2}

Step-by-step solution

Tollen's reagent consists of a solution of silver nitrate and ammonia.

Terminal alkynes react with tollen's reagent and form white color precipitate.

With Tollen's reagent (ammoniacal AgNO3{AgNO}_{3}), a white precipitate of silver salt is obtained.

H−C≡C−H+2AgNO3+2NH4OH→Ag−C≡C−AgSliveracetylide(whiteppt.)+2NH4NO3+H2OH - C ≡ C - H + 2{AgNO}_{3} + 2{NH}_{4}OH \to \mathop{Ag - C ≡ C - Ag}_{Sliveracetylide ( whiteppt. )} + 2{NH}_{4}{NO}_{3} + {H}_{2}O

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