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BITSAT 2024Paper 2
Exam
BITSAT
Year
2024
Paper
Paper 2
Subject
Chemistry
Chapter
Coordination Compounds

BITSAT 2024 · Paper 2 · Chemistry · Coordination Compounds

The type of isomerism present in nitropentammine chromium (III)...

The type of isomerism present in nitropentammine chromium (III) chloride is

Options

  1. Aoptical
  2. Blinkage
  3. Cionization
  4. Dpolymerisation.

Correct answer

B. linkage

Step-by-step solution

The chemical formula of nitropenta ammine chromium(III) chloride is: [Cr(NH3)5(NO2)]Cl2\left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_5\left(\mathrm{NO}_2\right)\right] \mathrm{Cl}_2 It can exist in following two structures [Cr(NH3)5(NO2)]Cl2\left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_5\left(\mathrm{NO}_2\right)\right] \mathrm{Cl}_2 and Pentaamminenitrochromium (III) chloride [Cr(NH3)5ONO]Cl2\left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_5 \mathrm{ONO}\right] \mathrm{Cl}_2 Pentaamminenitritochromium (III) chloride Therefore, the type of isomerism found in this compound is linkage isomerism as NO2\mathrm{NO}_2 group is linked through N as −NO2-\mathrm{NO}_2 or through O as ONO.
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