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BITSAT2016ChemistryIonic EquilibriumActual

For a sparingly soluble salt A_ p B_ q , the relationship of its solubility product L s K_ s p with its solubility (S) is

Options

  1. ALs K _ sp = S ^ pq ( pq )^ P + q
  2. BLs = S ^ p + q p ^ p q ^ q
  3. CLs K _ sp = S ^ p + q p ^ q q ^ p
  4. DLs K _ sp = S ^ pq p ^ P q ^ q

Correct answer

B. Ls = S ^ p + q p ^ p q ^ q

Step-by-step solution

ApBq pA _ Sp ⁺+ qB _ Sq Let the solubility be S mol / liter Thus, aligned K _ sp &= [ A ⁺ ]^ p [ B ⁻ ]^ q &=[ Sp ]^ p [ Sq ]^ q = p ^ p q ^ q ( S )^ p + q aligned

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