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BITSAT2010ChemistryIonic EquilibriumActual

The K _ sp of CuS , Ag ₂ ~S and HgS are 10⁻³¹, 10⁻⁴⁴ and 10⁻⁵⁴ respectively. The solubility of these sulphides are in the order :

Options

  1. AAg ₂ ~S > CuS > HgS
  2. BAgS > HgS > CuS
  3. CHgS > Ag ₂ ~S > CuS
  4. DCuS > Ag ₂ ~S > HgS

Correct answer

A. Ag ₂ ~S > CuS > HgS

Step-by-step solution

For CuS, solubility = (10⁻³¹ )^ 1 / 2 ; array l For Ag ₂ ~S = ( K _ sp 4 )^ 1 3 = ( 10⁻⁴⁴ 4 )^ 1 3 and for HgS = (10⁻⁵⁴ )^ 1 2 array

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