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COMEDK2025ChemistryAldehydes and KetonesActual

Aldol condensation reaction between which of the following pair of compounds followed by dehydration gives 3-phenylprop-2-en-1-al?

Options

  1. ABenzaldehyde and Acetaldehyde
  2. BBenzaldehyde and Benzalacetone
  3. CBenzaldehyde and Ethylacetate
  4. DBenzaldehyde and Acetophenone

Correct answer

A. Benzaldehyde and Acetaldehyde

Step-by-step solution

The target product is 3-phenylprop-2-en-1-al, which has the structure C₆H₅-CH=CH-CHO . This compound is an , -unsaturated aldehyde. Aldol condensation between an aldehyde containing an -hydrogen and another carbonyl compound followed by dehydration typically yields such products. The structure C₆H₅-CH=CH-CHO can be retrosynthetically broken down at the double bond into benzaldehyde ( C₆H₅CHO ) and acetaldehyde ( CH₃CHO ). The reaction proceeds as follows: Benzaldehyde ( C₆H₅CHO ) reacts with acetaldehyde ( CH₃CHO )

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