COMEDK2023Evening ShiftChemistryAldehydes and KetonesActual
Which one of the following compounds would not undergo Aldol condensation?
Options
- A2,2-Dimethyl butanal
- B2- Methyl pentanal
- C1- Phenyl propanone.
- DPhenyl ethanal
Correct answer
A. 2,2-Dimethyl butanal
Step-by-step solution
Aldol condensation requires the presence of at least one -hydrogen atom in the carbonyl compound. An -hydrogen is a hydrogen atom attached to the carbon atom adjacent to the carbonyl group. Analyzing the structures: 1. 2,2-Dimethylbutanal: The structure is CH₃-CH₂-C(CH₃)₂-CHO . The -carbon is the carbon atom attached to the aldehyde group. In this molecule, the -carbon is bonded to two methyl groups and the aldehyde group, meaning it has no hydrogen atoms attached to it. Thus, it lacks -hydrogens. 2. 2-Methylpentan